Home » Standard Temperature and Pressure Conditions
Standards

Standard Temperature and Pressure Conditions

Standard temperature and pressure conditions as well as normal temperature and pressure conditions are used as reference points in thermodynamics of gases. Normally standard and normal temperature pressure conditions are used for specifying vapor volume.

This is because, volume of a given number of vapor moles is a function of temperature and pressure conditions. Hence it becomes imperative to specify the corresponding temperature and pressure conditions for volume measurement, whenever gas quantity is specified in terms of gas volume.

Hence universally recognized reference temperature and pressure conditions can be easily used to specify gas volume measured at those conditions. This gas volume can be readily converted to number of moles or gas mass, as temperature and pressure of this standard reference point is easily known.

Values of standard temperature and pressure depend on the organization which defines them. Usually the standard pressure is close to atmospheric pressure and standard temperature is close to room temperature value.

Standard conditions for temperature and pressure are standard sets of conditions for experimental measurements to be established to allow comparisons to be made between different sets of data. The most used standards are those of the International Union of Pure and Applied Chemistry (IUPAC) and the National Institute of Standards and Technology (NIST), although these are not universally accepted standards. Other organizations have established a variety of alternative definitions for their standard reference conditions.

In chemistry, IUPAC has changed the definition of standard temperature and pressure (STP) in 1982:

  • Until 1982, STP was defined as a temperature of 273.15 K (0 °C, 32 °F) and an absolute pressure of exactly 1 atm (1.01325 × 105 Pa).
  • Since 1982, STP is defined as a temperature of 273.15 K (0 °C, 32 °F) and an absolute pressure of exactly 105 Pa (100 kPa, 1 bar).

STP should not be confused with the standard state commonly used in thermodynamic evaluations of the Gibbs energy of a reaction.

NIST uses a temperature of 20 °C (293.15 K, 68 °F) and an absolute pressure of 1 atm (14.696 psi, 101.325 kPa). This standard is also called normal temperature and pressure (abbreviated as NTP).

The International Standard Metric Conditions for natural gas and similar fluids are 288.15 K (15.00 °C; 59.00 °F) and 101.325 kPa.

In industry and commerce, standard conditions for temperature and pressure are often necessary to define the standard reference conditions to express the volumes of gases and liquids and related quantities such as the rate of volumetric flow (the volumes of gases vary significantly with temperature and pressure). However, many technical publications (books, journals, advertisements for equipment and machinery) simply state “standard conditions” without specifying them, often leading to confusion and errors. Good practice always incorporates the reference conditions of temperature and pressure.

Past use

Before 1918, many professionals and scientists using the metric system of units defined the standard reference conditions of temperature and pressure for expressing gas volumes as being 15 °C (288.15 K; 59.00 °F) and 101.325 kPa (1.00 atm; 760 Torr). During those same years, the most commonly used standard reference conditions for people using the imperial or U.S. customary systems was 60 °F (15.56 °C; 288.71 K) and 14.696 psi (1 atm) because it was almost universally used by the oil and gas industries worldwide. The above definitions are no longer the most commonly used in either system of units.

Current use

Many different definitions of standard reference conditions are currently being used by organizations all over the world. The table below lists a few of them, but there are more. Some of these organizations used other standards in the past. For example, IUPAC has, since 1982, defined standard reference conditions as being 0 °C and 100 kPa (1 bar), in contrast to its old standard of 0 °C and 101.325 kPa (1 atm).

Natural gas companies in Europe, Australia, and South America have adopted 15 °C (59 °F) and 101.325 kPa (14.696 psi) as their standard gas volume reference conditions. Also, the International Organization for Standardization (ISO), the United States Environmental Protection Agency (EPA) and National Institute of Standards and Technology (NIST) each have more than one definition of standard reference conditions in their various standards and regulations.

Table : Standard reference conditions in current use

Table 1 :

Defining OrganizationTemperature in 0CPressure in kPa
IUPAC0100.0
NIST, ISO 107800101.325
ISA, ISO 1344315101.325
EPA25101.325
SATP25100.0
CAG20100.0
SPE15100.0
ISO 501120101.3

Table 2 :

Defining OrganizationTemperature in 0FPressure in psi
SPE, OSHA6014.696
OPEC, U.S. EIA6014.73
U.S. Army Standard Metro5914.503
ISO 2314, ISO 3977-25914.696

Similar Articles:

Related Articles

Zone vs Class / Division

S Bharadwaj Reddy

ISA codes for Process Instrumentation

S Bharadwaj Reddy

Understanding Hazardous Area Classification

S Bharadwaj Reddy

RTD Standards

S Bharadwaj Reddy

Pressure Standards

S Bharadwaj Reddy

ATEX Standards

S Bharadwaj Reddy

Leave a Comment

This website uses cookies to improve your experience. We'll assume you're ok with this, but you can opt-out if you wish. Accept Read More

WordPress Image Lightbox